Chlorine types compared: liquid, bleach, cal-hypo, dichlor, trichlor and salt

All pool chlorine ends up as the same thing in the water: free chlorine. What differs is how strong the product is, how you dose it, and what it leaves behind — stabilizer, calcium or salt. Those leftovers decide which one suits your pool, so they are worked out here from the chemistry rather than guessed.

Chlorine types side by side

Doses per 10,000 US gallons, worked from label strength (liquids read as grams of chlorine per 100 ml). Side products are stoichiometry of the pure compound; trichlor’s 0.6 ppm CYA per ppm matches the PHTA committee’s published figure. Strength sources: HASA, Pool Essentials and Clorox data sheets, EPA labels 57787-18, 1258-161, 42177-80 and 36284-5.
TypeStrength on the label+1 ppm in 10,000 galAlso adds, per 1 ppm of chlorineEffect on pHUsual use
Liquid chlorine (sodium hypochlorite)10% or 12.5%10.2 fl oz (1.3 cups) of 12.5%About 1.65 ppm salt, once usedAlkaline in the jug; most of the rise reverses as the chlorine is used. A small upward drift is common.Daily dosing and shocking
Household bleach (plain, unscented)5–8.25% sodium hypochlorite21.3 fl oz (2.7 cups) of 6%About 1.65 ppm salt, once usedSame as liquid chlorineSmall pools and hot tubs; same chemical, weaker
Cal-hypo (calcium hypochlorite)65–73% available chlorine2.1 oz of 65%About 0.71 ppm calcium hardnessRaises pH when added; much of it reverses as the chlorine is usedGranular shock, pre-dissolved
Dichlor (sodium dichloroisocyanurate)55–56% (dihydrate); about 62% anhydrous2.4 oz of 56%About 0.91 ppm stabilizer (CYA)Close to neutral when added; mildly acidic over timeHot tubs; quick shock in pools
Trichlor (trichloroisocyanuric acid)90%1.5 oz (one 7 oz tablet ≈ 4.7 ppm)About 0.61 ppm stabilizer (CYA)Strongly acidic: pulls pH and alkalinity downTablets in a floater or feeder
Salt chlorine generatorMakes chlorine from salt kept at about 3,200–3,600 ppm (Hayward and Pentair targets)Set by cell output and run timeNothing net: the salt is turned back into salt as chlorine is usedNeutral on paper; pH often drifts up in practice, so expect to add acidContinuous dosing in pools
Non-chlorine shock (monopersulfate)Not chlorineAdds no free chlorineSulfateAcidic; can lower pH and alkalinity a littleOxidizing between chlorine doses; not a sanitizer

Bigger rises scale in a straight line — 3 ppm takes three times the 1 ppm figure. The full set for 1, 3, 5 and 10 ppm is in the pool chemical dose chart, and the worked pages do it for a whole pool: how much chlorine for a 10,000 gallon pool, how much chlorine for a 15,000 gallon pool and how much chlorine for a 20,000 gallon pool.

What “available chlorine” means

The percentage on a bag of granules or tablets is available chlorine: how much the product can oxidize, expressed as if it were chlorine gas, as a share of its weight. That is why trichlor is “90%” even though it is not 90% chlorine atoms, and why cal-hypo is sold at 65% one shelf over from 73%. Liquid strengths are usually read as grams of chlorine per 100 ml (the bleach trade’s “percent”), so 12.5% liquid holds about 125 g of chlorine per litre. Some jugs state 12.5% sodium hypochlorite by weight instead, which one supplier’s data sheet puts at about 142 g per litre — a little stronger.

grams of chlorine needed = ppm rise × litres of water ÷ 1,000
product needed = grams ÷ available-chlorine fraction

What each one leaves behind

This is the part that matters over a season. Every ppm of chlorine you add brings its carrier along, and chlorine is used up but the carrier is not.

Salt from hypochlorite: 2 × 58.44 ÷ 70.91 = 1.65 ppm per ppm FC
Calcium from cal-hypo: 100.09 ÷ (2 × 70.91) = 0.71 ppm CH per ppm FC
CYA from dichlor: 129.07 ÷ (2 × 70.91) = 0.91 ppm per ppm FC
CYA from trichlor: 129.07 ÷ (3 × 70.91) = 0.61 ppm per ppm FC

To see what that adds up to, imagine a pool that uses 2 ppm of chlorine a day for 90 days — 180 ppm in all — and gets every bit of it from one product:

Stoichiometry for 180 ppm of chlorine, before any water is replaced. Rain, backwashing and splash-out dilute all of these in real pools.
If all the chlorine came from…It would also add
Liquid chlorine or bleachAbout 297 ppm of salt
Cal-hypoAbout 127 ppm of calcium hardness
DichlorAbout 164 ppm of stabilizer
TrichlorAbout 109 ppm of stabilizer
Salt generatorNo net change; salt only leaves with splash-out, backwash and rain overflow

Salt is harmless at those levels (a salt pool runs ten times more on purpose). Calcium matters on plaster but is rarely a problem from cal-hypo alone. Stabilizer is the one that bites: the Model Aquatic Health Code caps it at 90 ppm in public pools, and the more CYA in the water, the more chlorine you need every day. A pool on tablets all summer can end up needing a partial drain — see how much water to drain to lower CYA.

How to choose

For algae, any chlorine works if you can reach and hold the level your stabilizer calls for. In practice that means liquid chlorine: reaching 16–20 ppm with dichlor or trichlor would add a lot of stabilizer at once. How much liquid chlorine to SLAM a pool works through it.

Storage and the never-mix rule

The CDC estimates that pool chemical injuries lead to 3,000–5,000 emergency department visits a year (MMWR, 2019). The rules that prevent most of them are simple:

  • Never mix chemicals, especially chlorine with acid (that releases chlorine gas), and never mix two kinds of chlorine. Cal-hypo and trichlor in particular must not meet; the CDC’s storage poster says not to mix different chlorine products.
  • Store acid and chlorine apart, in their original labelled containers, in a cool, dry, ventilated place out of the sun, with liquids on low shelves. The CDC toolkit says to keep them below 95°F (35°C).
  • One scoop, one chemical. Don’t reuse containers or measuring cups across products.
  • Add chemical to water, never water to chemical, one product at a time, with the pump running, and keep children away.
  • The label is the law. Pool chlorine is an EPA-registered pesticide; follow the label’s dose, swimming limits and storage.
CautionFollow the product label. Add chemicals to water, never water to chemicals. Never mix chemicals — especially chlorine and acid, or two kinds of chlorine — and never put them in the same bucket or scoop. Add one at a time, with the pump running, and retest after the water has circulated. These are estimates for pool and spa water, never for drinking water.

Frequently asked questions

Which types of pool chlorine add stabilizer?

Only the stabilized ones: trichlor (about 0.6 ppm CYA per ppm of chlorine) and dichlor (about 0.9). Liquid chlorine, bleach, cal-hypo and salt generators add none.

Is pool liquid chlorine stronger than bleach?

Yes, usually about twice as strong: pool chlorine is 10–12.5%, household bleach 5–8.25%. It is the same chemical, sodium hypochlorite, so you simply use more bleach for the same rise.

Can I switch from chlorine tablets to liquid chlorine mid-season?

Yes. Stop the tablets, rinse the feeder, and dose liquid by your free chlorine test. Stabilizer already in the water stays, so keep chlorine at the level your CYA calls for.

Sources